Qualitative and quantitative analysis
Is milk adulterated (identity) and how much fat does it hold (amount)? Both are analysis questions.
Analytical chemistry finds out what a substance contains (qualitative) and how much (quantitative).
In the figure : Qualitative and quantitative.
Rule 1: Qualitative analysis — Identifying ions or elements: flame test, precipitation, colour change, Lassaigne test.
- Easy : Na⁺: golden-yellow flame.
- Medium : Cl⁻ + AgNO₃ ⇒ white AgCl.
- Exam-type : Fe³⁺ + SCN⁻ ⇒ blood-red.
Rule 2: Quantitative analysis — Measuring amounts: titration (volumetric), gravimetry (weighing precipitate), spectrometry (light absorption).
- Easy : 20 mL of 0.1 M HCl neutralises 25 mL NaOH ⇒ 0.08 M.
- Medium : SO₄²⁻ from the mass of BaSO₄.
- Exam-type : Concentration from colour intensity.
Rule 3: Choosing a method — Based on sample size, expected amount (major/trace), accuracy needed and cost.
- Easy : Large amount ⇒ titration.
- Medium : Trace (ppm) ⇒ spectrometry.
- Exam-type : Identity first, amount next.
Calculation: molarity of NaOH by titration
- Step 1: M₁V₁ = M₂V₂ (1 : 1 reaction).
- Step 2: 0.1 × 20 = M × 25.
- Step 3: M = 2 ÷ 25 = 0.08 M.
CET level (MCQ)
- CET 1) A quantitative method? 1) flame test 2) titration 3) precipitate colour 4) smell — Answer: 2).
- CET 2) A qualitative question asks? 1) how much 2) what 3) where 4) when — Answer: 2).
Real-life use: Food adulteration, water testing, drug quality.
Qualitative = what; quantitative = how much; titration M₁V₁ = M₂V₂.
Thinking a flame test gives amounts; it only identifies.
M₁V₁ = M₂V₂ in titration holds only for 1 : 1 reactions.
Memory clue: "quality = what, quantity = how much".
Spot the difference
| Item | Qualitative | Quantitative |
|---|---|---|
| Answer | what | how much |
| Example | flame test | titration |
Practice questions
- 1What is analytical chemistry?
- 2Two qualitative tests.
- 3Two quantitative methods.
- 4Test for Cl⁻?
- 520 mL 0.1 M HCl vs 25 mL NaOH ⇒ M?
- 6What is titration?
- 7When use spectrometry?
- 8Which analysis comes first?
Show answers (try them yourself first)
- 1Finding what and how much.
- 2Flame and precipitation.
- 3Titration and gravimetry.
- 4AgNO₃ ⇒ white precipitate.
- 50.08 M.
- 6Finding an unknown with a known solution.
- 7For trace amounts.
- 8Qualitative.
Scientific notation, accuracy, precision and errors
A scale showing 1.9 kg for 2 kg is an error; if it always shows 1.9 it is precise but not accurate.
Scientific notation: N × 10ⁿ (1 ≤ N < 10). Accuracy: closeness to the true value. Precision: closeness of repeated measurements.
In the figure : Accuracy and precision.
Rule 1: Scientific notation — Decimal moved right ⇒ negative n; left ⇒ positive n. Multiply: add powers; divide: subtract.
- Easy : 0.000345 = 3.45 × 10⁻⁴.
- Medium : (3 × 10⁴)(2 × 10³) = 6 × 10⁷.
- Exam-type : 0.5 mol = 3.011 × 10²³ particles.
Rule 2: Accuracy versus precision — Four cases: both; precise only (systematic error); accurate only (right average); neither.
- Easy : All 9.8 g (true 10.0) ⇒ precise, not accurate.
- Medium : 9.7, 10.3, 10.0 ⇒ accurate on average.
- Exam-type : 10.0, 10.0, 10.0 ⇒ both.
Rule 3: Types of errors — Systematic (one direction) and random. Absolute error = |measured − true|; % error = absolute ÷ true × 100.
- Easy : True 10.0, measured 9.8 ⇒ 0.2, 2 %.
- Medium : A wrong zero ⇒ systematic.
- Exam-type : Reading variation ⇒ random.
Calculation: percent error
- Step 1: Absolute error = |9.8 − 10.0| = 0.2.
- Step 2: ÷ true value = 0.2 ÷ 10.0 = 0.02.
- Step 3: × 100 = 2 %.
CET level (MCQ)
- CET 1) 0.000345 = ? 1) 3.45×10⁻³ 2) 3.45×10⁻⁴ 3) 34.5×10⁻⁵ 4) 3.45×10⁴ — Answer: 2).
- CET 2) A systematic error lowers? 1) precision 2) accuracy 3) both 4) neither — Answer: 2).
Real-life use: Weighing scales, lab measurement, quality control.
N × 10ⁿ; accurate = near true; precise = near each other; % error ÷ true.
Treating accuracy and precision as the same.
Percent error is divided by the true value, not the measured one.
Memory clue: "precision = repeatability".
Spot the difference
| Item | Accuracy | Precision |
|---|---|---|
| Meaning | near true | near each other |
| Error | systematic | random |
Practice questions
- 10.000345 in scientific notation.
- 2(3×10⁴)(2×10³)?
- 3What is accuracy?
- 4What is precision?
- 5True 10.0, measured 9.8 ⇒ % error?
- 6Example of systematic error.
- 79.8, 9.8, 9.8 (true 10.0) ⇒ ?
- 8Particles in 0.5 mol?
Show answers (try them yourself first)
- 13.45 × 10⁻⁴.
- 26 × 10⁷.
- 3Closeness to the true value.
- 4Closeness among measurements.
- 52 %.
- 6A wrong zero setting.
- 7Precise, not accurate.
- 83.011 × 10²³.
Significant figures and rounding off
A scale saying 2.50 kg rather than 2.5 kg shows how finely it measured.
Significant figures: the certain digits plus the last uncertain one. An answer cannot be more precise than the measurement.
In the figure : Significant figures.
Rule 1: Counting rules — Non-zero digits count; middle zeros count; leading zeros do not; trailing zeros after a decimal count; 4500 has 2 (4.500×10³ has 4).
- Easy : 0.00345: 3.
- Medium : 2.0050: 5.
- Exam-type : 0.0300: 3.
Rule 2: Rules in arithmetic — Multiply/divide: fewest significant figures. Add/subtract: fewest decimal places. Exact counts (5 students) have no limit.
- Easy : 2.5 × 3.42 = 8.55 ⇒ 8.6 (2 s.f.).
- Medium : 12.11 + 18.0 + 1.012 = 31.122 ⇒ 31.1.
- Exam-type : Exact numbers are unlimited.
Rule 3: Rounding off — First dropped digit less than 5 ⇒ the last kept digit stays; 5 or more ⇒ add 1 to it (textbook rule).
- Easy : 3.142 ⇒ 3.14 (2 < 5).
- Medium : 7.465 ⇒ 7.47 (5 ⇒ +1).
- Exam-type : 6.78 ⇒ 6.8.
Calculation: 2.5 × 3.42
- Step 1: 2.5 × 3.42 = 8.55.
- Step 2: 2.5 has 2 s.f. ⇒ answer has 2 s.f.
- Step 3: In 8.55 the dropped digit is 5 ⇒ add 1 ⇒ 8.6.
CET level (MCQ)
- CET 1) Significant figures in 0.0300? 1) 1 2) 2 3) 3 4) 4 — Answer: 3).
- CET 2) 12.11 + 18.0 + 1.012 = ? 1) 31.122 2) 31.12 3) 31.1 4) 31 — Answer: 3).
Real-life use: Lab reports, calculations, instrument readings.
No leading zeros; add = decimals; multiply = sig. figs.
Counting sig. figs in addition; use decimal places there.
4500 has no decimal point ⇒ its end zeros are not significant (2 s.f.); write 4.500 × 10³ for 4.
Memory clue: "× ÷ = figures, + − = decimals".
Spot the difference
| Operation | Rule |
|---|---|
| × ÷ | fewest sig. figs |
| + − | fewest decimals |
Practice questions
- 1Sig. figs of 0.00345?
- 2Sig. figs of 2.0050?
- 32.5 × 3.42?
- 412.11 + 18.0 + 1.012?
- 5Round 2.345 to 3 s.f.
- 6Significant figures in 4500?
- 7Rule for addition?
- 8S.f. of exact numbers?
Show answers (try them yourself first)
- 13.
- 25.
- 38.6.
- 431.1.
- 52.35 (5 ⇒ +1).
- 62 (no decimal point, so end zeros do not count).
- 7Fewest decimal places.
- 8Unlimited.
Percent composition, empirical and molecular formula
'Carbs 70 %' on a packet is a composition in percent.
Percent composition = mass of element ÷ total × 100. Empirical formula (EF): simplest whole-number ratio of atoms. Molecular formula (MF) = (EF) × n.
In the figure : % ⇒ EF ⇒ MF.
Rule 1: Percent composition — In Fe₂O₃ the Fe is (2 × 56) ÷ 160 × 100 = 70 %.
- Easy : H in H₂O: 2/18 = 11.1 %.
- Medium : Na in NaCl: 23/58.5 = 39.3 %.
- Exam-type : Fe₂O₃: Fe 70 %, O 30 %.
Rule 2: Steps for EF — Take 100 g ⇒ g ÷ M ⇒ moles ⇒ ÷ smallest ⇒ whole numbers (.5 ⇒ ×2; .33 ⇒ ×3).
- Easy : 40 % C, 6.7 % H, 53.3 % O ⇒ CH₂O.
- Medium : 85.7 % C, 14.3 % H ⇒ CH₂.
- Exam-type : 52.9 % Al, 47.1 % O ⇒ Al₂O₃.
Rule 3: Getting MF — n = M ÷ M(EF); MF = (EF)n. CH₂O with M = 180 ⇒ n = 6 ⇒ C₆H₁₂O₆.
- Easy : CH₂, M = 84 ⇒ C₆H₁₂.
- Medium : CH, M = 78 ⇒ C₆H₆.
- Exam-type : HO, M = 34 ⇒ H₂O₂.
Calculation: 85.7 % C, 14.3 % H, M = 84
- Step 1: C = 85.7/12 = 7.14; H = 14.3/1 = 14.3.
- Step 2: ÷ 7.14 ⇒ C : H = 1 : 2 ⇒ EF = CH₂ (14).
- Step 3: n = 84 ÷ 14 = 6 ⇒ C₆H₁₂.
CET level (MCQ)
- CET 1) CH₂O with M = 60 ⇒ MF? 1) C₂H₄O₂ 2) CH₂O 3) C₃H₆O₃ 4) C₆H₁₂O₆ — Answer: 1).
- CET 2) % Fe in Fe₂O₃? 1) 30 2) 56 3) 70 4) 72 — Answer: 3).
Real-life use: Drug purity, mineral analysis.
Take 100 g; moles; ÷ smallest; MF = EF × n.
Treating percentages as the ratio; convert to moles first.
1.33 ⇒ ×3 (not 4); 1.5 ⇒ ×2.
Memory clue: "% → g → mol → ratio".
Spot the difference
| Item | EF | MF |
|---|---|---|
| Glucose | CH₂O | C₆H₁₂O₆ |
| Benzene | CH | C₆H₆ |
| H₂O₂ | HO | H₂O₂ |
Practice questions
- 1% Fe in Fe₂O₃?
- 2% H in H₂O?
- 3What is EF?
- 4EF for 40 % C, 6.7 % H, 53.3 % O?
- 5MF: EF CH₂O, M = 180.
- 685.7 % C, 14.3 % H, M = 84 ⇒ MF?
- 7What if a ratio is 1.5?
- 8CH, M = 78 ⇒ ?
Show answers (try them yourself first)
- 170 %.
- 211.1 %.
- 3Simplest whole-number ratio.
- 4CH₂O.
- 5C₆H₁₂O₆.
- 6C₆H₁₂.
- 7Multiply by 2.
- 8C₆H₆.
Stoichiometric calculations
A cake recipe fixes eggs-to-flour ratios; a chemical equation fixes mole ratios.
Stoichiometry: using mole ratios from a balanced equation to find reactant and product amounts.
In the figure : Mole map.
Rule 1: Mole map — n = m ÷ M = particles ÷ 6.022×10²³ = V(STP) ÷ 22.4 = M × V(L).
- Easy : 10 g CaCO₃ = 0.1 mol.
- Medium : 0.1 mol CO₂ = 2.24 L (STP).
- Exam-type : 0.2 M in 0.5 L = 0.1 mol.
Rule 2: Mass–mass problems — Balance ⇒ moles of given ⇒ ratio ⇒ moles of wanted ⇒ mass.
- Easy : CaCO₃ → CaO + CO₂: 10 g ⇒ 4.4 g CO₂.
- Medium : 2Al + 6HCl: 5.4 g Al ⇒ 0.3 mol H₂.
- Exam-type : N₂ + 3H₂: 56 g N₂ ⇒ 68 g NH₃.
Rule 3: Volume and particle problems — For gases at STP 1 mol = 22.4 L; Avogadro gives particles. At equal T, P gas volume ∝ moles.
- Easy : 5.4 g Al ⇒ 6.72 L H₂.
- Medium : 2H₂ + O₂: 4 L H₂ needs 2 L O₂.
- Exam-type : 0.1 mol ⇒ 6.022×10²² molecules.
Calculation: H₂ (STP) from 5.4 g Al + HCl
- Step 1: 2Al + 6HCl → 2AlCl₃ + 3H₂; n(Al) = 5.4 ÷ 27 = 0.2 mol.
- Step 2: 2 : 3 ⇒ H₂ = 0.2 × 3/2 = 0.3 mol.
- Step 3: V = 0.3 × 22.4 = 6.72 L.
CET level (MCQ)
- CET 1) CO₂ (STP) from 10 g CaCO₃? 1) 1.12 L 2) 2.24 L 3) 4.48 L 4) 22.4 L — Answer: 2).
- CET 2) In 2Al : 3H₂, 0.2 mol Al gives H₂? 1) 0.2 2) 0.3 3) 0.4 4) 0.6 — Answer: 2).
Real-life use: Industrial yield, fertiliser amounts, fuel combustion.
Balanced equation ⇒ mole ratio; 22.4 L; 6.022×10²³.
Using grams directly in the ratio; use moles first.
22.4 L is only at STP (0 °C, 1 atm).
Memory clue: "grams → mol → mol → grams".
Spot the difference
| Quantity | Formula |
|---|---|
| Moles | m ÷ M |
| Particles | n × 6.022×10²³ |
| Volume | n × 22.4 L |
Practice questions
- 1Moles in 10 g CaCO₃?
- 2Mass of CO₂ from it?
- 3H₂ in L from 5.4 g Al?
- 4Molecules in 0.1 mol?
- 5NH₃ from 56 g N₂?
- 6O₂ for 4 L H₂?
- 7What is STP?
- 8Why not grams directly?
Show answers (try them yourself first)
- 10.1 mol.
- 24.4 g.
- 36.72 L.
- 46.022×10²².
- 568 g.
- 62 L.
- 70 °C and 1 atm.
- 8Equations are in moles.
Limiting reagent and percent yield
With 10 bread slices and 3 cheese slices you make only 3 sandwiches; cheese is limiting.
Limiting reagent is used up first and fixes the product. Percent yield = actual ÷ theoretical × 100.
In the figure : Limiting reagent.
Limiting reagent and percent yield
In the app you can move this figure with your finger.
Open in the appRule 1: Finding it — Moles ÷ coefficient for each; the smaller value is limiting.
- Easy : 2H₂ + O₂: 2/2 = 1; 0.5/1 = 0.5 ⇒ O₂.
- Medium : N₂ 0.1, H₂ 0.5: 0.1/1 vs 0.5/3 = 0.167 ⇒ N₂.
- Exam-type : Equal values ⇒ both fully used.
Rule 2: Product and leftover — Product from the limiting reagent; leftover = initial − used.
- Easy : 0.5 mol O₂ ⇒ 1 mol H₂O = 18 g.
- Medium : H₂ left 2 − 1 = 1 mol = 2 g.
- Exam-type : 0.1 mol N₂ ⇒ 0.2 mol NH₃ = 3.4 g.
Rule 3: Percent yield — % yield = (actual ÷ theoretical) × 100; always ≤ 100 %.
- Easy : 3.0 g / 3.4 g = 88.2 %.
- Medium : Theoretical 20 g, actual 15 g = 75 %.
- Exam-type : Above 100 % = wet or impure product.
Calculation: 4 g H₂ and 16 g O₂
- Step 1: n(H₂) = 2 mol; n(O₂) = 0.5 mol.
- Step 2: 2/2 = 1; 0.5/1 = 0.5 ⇒ O₂ is limiting.
- Step 3: H₂O = 2 × 0.5 = 1 mol = 18 g; 1 mol H₂ is left.
CET level (MCQ)
- CET 1) 2H₂ + O₂: 4 g H₂ + 16 g O₂ ⇒ H₂O? 1) 9 g 2) 18 g 3) 20 g 4) 36 g — Answer: 2).
- CET 2) Theoretical 20 g, actual 15 g ⇒ % yield? 1) 25 2) 60 3) 75 4) 133 — Answer: 3).
Real-life use: Cost control in factories, drug synthesis.
Moles ÷ coefficient ⇒ smaller = limiting; % yield ≤ 100.
Calling the reagent with fewer grams limiting; check moles.
Forgetting to divide by the coefficient gives the wrong limiting reagent.
Memory clue: "smallest share = limiting".
Spot the difference
| Item | Limiting | Excess |
|---|---|---|
| State | used up | left over |
| Decides | product | nothing |
Practice questions
- 1What is a limiting reagent?
- 24 g H₂ + 16 g O₂ ⇒ limiting?
- 3H₂O formed?
- 4H₂ left over?
- 5NH₃ from 2.8 g N₂ + 1 g H₂?
- 6Actual 3.0 g, theoretical 3.4 g ⇒ %?
- 7Why not above 100 %?
- 8Why divide by the coefficient?
Show answers (try them yourself first)
- 1The reactant used up first.
- 2O₂.
- 318 g.
- 41 mol (2 g).
- 53.4 g.
- 688.2 %.
- 7Actual ≤ theoretical.
- 8To match the equation ratio.
Concentration of solutions
One spoon versus three spoons of sugar in tea is a difference in concentration.
Molarity M = mol ÷ L of solution. Molality m = mol ÷ kg of solvent. Mole fraction x = n₁ ÷ (n₁ + n₂). ppm = parts per 10⁶.
In the figure : Concentration units.
Concentration of solutions
In the app you can move this figure with your finger.
Open in the appRule 1: Molarity and dilution — M = n ÷ V(L). In dilution moles stay constant: M₁V₁ = M₂V₂.
- Easy : 4 g NaOH in 500 mL ⇒ 0.2 M.
- Medium : 2 M, 100 mL ⇒ 0.5 M needs 400 mL.
- Exam-type : 0.5 L of 0.04 M NaOH ⇒ 0.8 g.
Rule 2: Molality and mole fraction — Molality is temperature-independent; molarity is not. Mole fractions add to 1.
- Easy : 4 g NaOH in 100 g water ⇒ 1 m.
- Medium : x(NaOH) = 0.1 ÷ 5.656 = 0.0177.
- Exam-type : x₁ + x₂ = 1.
Rule 3: Percent and ppm — Mass % = g/100 g; ppm = g/10⁶ g ≈ mg/L (in water).
- Easy : 5 mg/L ≈ 5 ppm.
- Medium : 10 g salt in 90 g water ⇒ 10 %.
- Exam-type : 0.2 ppm Cl₂ ⇒ 0.2 g/m³.
Calculation: dilute 100 mL of 2 M to 0.5 M
- Step 1: M₁V₁ = M₂V₂ ⇒ 2 × 100 = 0.5 × V₂.
- Step 2: V₂ = 200 ÷ 0.5 = 400 mL.
- Step 3: Water to add = 400 − 100 = 300 mL.
CET level (MCQ)
- CET 1) 4 g NaOH in 500 mL ⇒ M? 1) 0.1 2) 0.2 3) 0.4 4) 2 — Answer: 2).
- CET 2) Independent of temperature? 1) M 2) N 3) m 4) V — Answer: 3).
Real-life use: Drug solutions, fertiliser mixes, water testing.
M = mol/L; m = mol/kg solvent; M₁V₁ = M₂V₂; ppm = mg/L.
Using kg of solution in molality; it is kg of solvent.
In M, V is litres of solution, not of water.
Memory clue: "M = Litre of solution, m = kg of solvent".
Spot the difference
| Unit | Formula | Temperature |
|---|---|---|
| M | mol/L | depends |
| m | mol/kg | independent |
| x | n₁/Σn | independent |
Practice questions
- 14 g NaOH in 500 mL ⇒ M?
- 24 g NaOH in 100 g water ⇒ m?
- 3Mole fraction of NaOH?
- 4How to make 0.5 M from 100 mL of 2 M?
- 55 mg/L = ? ppm
- 6Why does M depend on temperature?
- 7Sum of mole fractions?
- 8NaOH in 0.5 L of 0.04 M?
Show answers (try them yourself first)
- 10.2 M.
- 21 m.
- 30.0177.
- 4Add 300 mL of water.
- 55 ppm.
- 6Volume changes.
- 71.
- 80.8 g.
Quick revision of the whole lesson
| Concept | Key formula / fact | ||
|---|---|---|---|
| Qualitative/quantitative | what / how much | ||
| % error | measured − true | ÷ true × 100 | |
| Sig. figs | × ÷ figures; + − decimals | ||
| EF → MF | MF = EF × n | ||
| Mole | m ÷ M = V ÷ 22.4 | ||
| Limiting | smallest mol ÷ coeff. | ||
| % yield | actual ÷ theoretical × 100 | ||
| Dilution | M₁V₁ = M₂V₂ |
🚀 Quick revision of the whole lesson
In the app you can move this figure with your finger.
Open in the app🎯 Most important points for the exam
- Qualitative/quantitative.
- Accuracy, errors.
- Significant figures.
- EF and MF.
- Stoichiometry.
- Limiting reagent.
- Concentration.
understand the idea → remember the formula → solve the example → solve problems yourself.