The nucleus: composition, size and classes of nuclides
The americium-241 in a smoke detector and sunlight are both nuclear energy at work.
A nucleus = protons (Z) + neutrons (N); mass number A = Z + N. An atom with a specific Z and A is a nuclide.
In the figure : Classes of nuclides.
Rule 1: Classification — Isotopes: same Z; isobars: same A; isotones: same N; isomers: same A and Z but different energy state.
- Easy : ¹²C and ¹⁴C are isotopes.
- Medium : ¹⁴C and ¹⁴N are isobars.
- Exam-type : ¹³C and ¹⁴N are isotones (N = 7).
Rule 2: Size of the nucleus — r = r₀A^(1/3), r₀ = 1.33 fm (1.33 × 10⁻¹⁵ m in the textbook; some books use 1.2 fm). Volume ∝ A ⇒ nearly constant density ≈ 1.7 × 10¹⁷ kg/m³.
- Easy : A = 8 ⇒ r = 1.33 × 2 = 2.66 fm.
- Medium : A = 27 ⇒ r = 1.33 × 3 ≈ 4.0 fm.
- Exam-type : A = 64 ⇒ r = 1.33 × 4 = 5.32 fm.
Rule 3: Particles — Proton (+1, 1.0073 u), neutron (0, 1.0087 u), electron (−1, 0.00055 u). The nucleus holds nearly all the mass.
- Easy : ²³⁵U: Z = 92, N = 143.
- Medium : ¹⁴C: N = 8.
- Exam-type : ⁵⁶Fe: Z = 26, N = 30.
Calculation: radius of a nucleus with A = 64
- Step 1: r = r₀A^(1/3) = 1.33 × 64^(1/3).
- Step 2: 64^(1/3) = 4.
- Step 3: r = 1.33 × 4 = 5.32 fm.
CET level (MCQ)
- CET 1) ¹⁴C and ¹⁴N are? 1) isotopes 2) isobars 3) isotones 4) isomers — Answer: 2).
- CET 2) Nuclear density is? 1) depends on A 2) nearly constant 3) Z² 4) 1/A — Answer: 2).
Real-life use: Smoke detectors, medical imaging, energy.
A = Z + N; r = 1.33 A^(1/3) fm; density ≈ 1.7×10¹⁷.
Swapping isotopes and isobars.
Electrons are not counted in A.
Memory clue: "iso-tope = same place Z, iso-bar = same weight A".
Spot the difference
| Class | Same | Example |
|---|---|---|
| Isotopes | Z | ¹²C, ¹⁴C |
| Isobars | A | ¹⁴C, ¹⁴N |
| Isotones | N | ¹³C, ¹⁴N |
Practice questions
- 1What is a nuclide?
- 2What are isobars?
- 3Radius for A = 27?
- 4N in ²³⁵U?
- 5Nuclear density?
- 6Why constant density?
- 7What are isomers?
- 8What does A count?
Show answers (try them yourself first)
- 1An atom of specific Z and A.
- 2Same A.
- 3≈ 4.0 fm.
- 4143.
- 5≈ 1.7 × 10¹⁷ kg/m³.
- 6Volume ∝ A.
- 7Same A and Z, different energy.
- 8Protons + neutrons.
Nuclear stability, N/Z ratio and magic numbers
Lead and gold are stable while uranium slowly changes — stability differs from nucleus to nucleus.
About 270 nuclides are stable; they lie in the band of stability on an N vs Z plot. N/Z ≈ 1 for light, ≈ 1.5 for heavy nuclei.
In the figure : Band of stability.
Rule 1: Even–odd rule — Even-Z even-N most stable (about 160); even-odd/odd-even (about 100); odd-odd only 4 stable: ²H, ⁶Li, ¹⁰B, ¹⁴N.
- Easy : ⁴He, ¹²C, ¹⁶O are even-even.
- Medium : ⁹Be is even-odd.
- Exam-type : ¹⁴N is odd-odd (exception).
Rule 2: N/Z ratio — Too many neutrons ⇒ β⁻ decay (n → p). Too few ⇒ β⁺ or K-capture (p → n). Z > 83 ⇒ α decay.
- Easy : ¹⁴C (N/Z = 1.33) ⇒ β⁻.
- Medium : ¹¹C (N/Z = 0.83) ⇒ β⁺.
- Exam-type : ²³⁸U ⇒ α.
Rule 3: Magic numbers and forces — 2, 8, 20, 28, 50, 82, 126 protons or neutrons ⇒ extra stable (closed shell). Nuclear force: strong, short-range (~2 fm), charge-independent.
- Easy : ⁴He: Z = N = 2 doubly magic.
- Medium : ²⁰⁸Pb: 82 and 126.
- Exam-type : ¹⁶O: 8 and 8.
Reasoning: decay mode of ¹⁴C
- Step 1: Z = 6, N = 8 ⇒ N/Z = 1.33.
- Step 2: Stable ≈ 1 for light nuclei ⇒ neutron-rich.
- Step 3: n → p + e⁻ + ν̄ ⇒ β⁻ decay.
CET level (MCQ)
- CET 1) A magic number? 1) 6 2) 20 3) 30 4) 100 — Answer: 2).
- CET 2) A stable odd-odd nucleus? 1) ¹²C 2) ¹⁴N 3) ¹⁶O 4) ⁴He — Answer: 2).
Real-life use: Reactor design, isotope research.
Magic: 2, 8, 20, 28, 50, 82, 126; N-rich ⇒ β⁻; N-poor ⇒ β⁺.
Assuming N/Z is always 1; it is 1.5 in heavy nuclei.
The four stable odd-odd nuclei: ²H, ⁶Li, ¹⁰B, ¹⁴N.
Memory clue: "2-8-20-28-50-82-126".
Spot the difference
| Condition | Decay |
|---|---|
| too many n | β⁻ |
| too few n | β⁺ / K |
| Z > 83 | α |
Practice questions
- 1What is the band of stability?
- 2List the magic numbers.
- 3Decay of ¹⁴C?
- 4Decay of ¹¹C?
- 5Four stable odd-odd nuclei.
- 6Properties of nuclear force.
- 7Why is ²⁰⁸Pb special?
- 8Z > 83 ⇒ ?
Show answers (try them yourself first)
- 1N–Z band of stable nuclides.
- 22, 8, 20, 28, 50, 82, 126.
- 3β⁻.
- 4β⁺ or K-capture.
- 5²H, ⁶Li, ¹⁰B, ¹⁴N.
- 6Strong, short-range.
- 7Doubly magic (82, 126).
- 8α decay.
Mass defect and binding energy
A built wall is more stable than loose bricks; assembling nucleons releases energy.
Mass defect Δm = (Zmₚ + Nmₙ) − m(nucleus). Binding energy = Δm × 931.5 MeV/u (textbook: 931.4). BE per nucleon is the stability measure.
In the figure : BE/A curve.
Rule 1: Δm and E — E = Δm c². 1 u = 931.5 MeV; 1 g = 9 × 10¹³ J. mₚ = 1.007276 u, mₙ = 1.008665 u.
- Easy : ⁴He: Δm = 0.030376 u.
- Medium : BE = 28.3 MeV.
- Exam-type : BE/A = 7.07 MeV.
Rule 2: BE/A curve — Peak near ⁵⁶Fe (≈ 8.8 MeV). Joining light nuclei (fusion) or splitting heavy ones (fission) releases energy.
- Easy : ²H: 1.1; ⁴He: 7.07.
- Medium : ⁵⁶Fe: 8.79, most stable.
- Exam-type : ²³⁸U: 7.57.
Rule 3: Stability and the curve — Higher BE/A ⇒ more stable. Peaks at ⁴He, ¹²C, ¹⁶O ⇒ magic/α-particle structure.
- Easy : ⁴He >> ²H.
- Medium : ⁵⁶Fe > ²³⁸U.
- Exam-type : Light ⇒ fusion pays.
Calculation: BE/A of ⁴He
- Step 1: Δm = 2(1.007276) + 2(1.008665) − 4.001506 = 0.030376 u.
- Step 2: BE = 0.030376 × 931.5 = 28.3 MeV.
- Step 3: BE/A = 28.3 ÷ 4 = 7.07 MeV.
CET level (MCQ)
- CET 1) Highest BE/A? 1) ²H 2) ⁵⁶Fe 3) ²³⁸U 4) ⁴He — Answer: 2).
- CET 2) 1 u = ? MeV 1) 93.15 2) 931.5 3) 9315 4) 0.931 — Answer: 2).
Real-life use: Nuclear power, stars, energy sources.
1 u = 931.5 MeV; ⁴He 7.07; ⁵⁶Fe 8.79.
Confusing total BE with BE/A.
Use the nuclear mass (or account for electrons) when finding Δm.
Memory clue: "iron = the peak".
Spot the difference
| Item | Fission | Fusion |
|---|---|---|
| Nuclei | heavy | light |
| BE/A | rises | rises |
Practice questions
- 1What is mass defect?
- 21 u = ? MeV
- 3BE of ⁴He?
- 4BE/A of ⁴He?
- 5Most stable nucleus?
- 6Why does fusion release energy?
- 7Energy from 1 g mass?
- 8Why does BE/A matter?
Show answers (try them yourself first)
- 1Sum of nucleon masses − nuclear mass.
- 2931.5 MeV.
- 328.3 MeV.
- 47.07 MeV.
- 5⁵⁶Fe.
- 6BE/A rises.
- 79 × 10¹³ J.
- 8It measures stability.
Radioactivity and modes of decay
In a smoke alarm α particles ionise air; smoke blocks them and triggers the alarm.
Radioactivity: an unstable nucleus emits α, β or γ and becomes stable (Becquerel, 1896).
In the figure : Decay modes.
Rule 1: α and β decay — α: ⁴He, A − 4, Z − 2. β⁻: n → p + e⁻ + ν̄, Z + 1. β⁺: p → n + e⁺ + ν, Z − 1. A is unchanged in β.
- Easy : ²³⁸U → ²³⁴Th + α.
- Medium : ¹⁴C → ¹⁴N + e⁻.
- Exam-type : ²²Na → ²²Ne + e⁺.
Rule 2: γ and K-capture — γ: electromagnetic photon, no change in A or Z. K-capture: the nucleus takes a K-shell electron ⇒ Z − 1.
- Easy : ⁶⁰Co* → ⁶⁰Co + γ.
- Medium : ⁷Be + e⁻ → ⁷Li.
- Exam-type : γ energy in MeV.
Rule 3: Penetration and ionisation — Ionising power: α > β > γ; penetration: γ > β > α. α is stopped by paper, β by aluminium, γ by thick lead.
- Easy : α: helium nucleus, +2.
- Medium : β: e⁻ or e⁺.
- Exam-type : γ: no charge.
Calculation: ²³⁸U (Z = 92) ⇒ ²⁰⁶Pb (Z = 82)
- Step 1: ΔA = 238 − 206 = 32 ⇒ α = 32 ÷ 4 = 8.
- Step 2: 8α gives Z = 92 − 16 = 76; need 82 ⇒ gain of 6.
- Step 3: 6 β⁻ decays.
CET level (MCQ)
- CET 1) After α emission A, Z change by? 1) −2, −4 2) −4, −2 3) −4, +2 4) 0, −2 — Answer: 2).
- CET 2) Most penetrating? 1) α 2) β 3) γ 4) proton — Answer: 3).
Real-life use: Smoke alarms, cancer therapy, industrial thickness gauging.
α: A−4, Z−2; β⁻: Z+1; β⁺: Z−1; γ: no change.
Thinking A changes in β decay.
²³⁸U ⇒ ²⁰⁶Pb: 8α + 6β⁻.
Memory clue: "α: 4-2; β⁻: +1".
Spot the difference
| Ray | Charge | Penetration |
|---|---|---|
| α | +2 | low |
| β | −1 | medium |
| γ | 0 | high |
Practice questions
- 1Change in A, Z in α decay?
- 2What happens in β⁻?
- 3What are γ rays?
- 4²³⁸U ⇒ ²⁰⁶Pb: α and β?
- 5What is K-capture?
- 6Order of penetration?
- 7What stops α?
- 8Z in β⁺?
Show answers (try them yourself first)
- 1−4, −2.
- 2n → p + e⁻ + ν̄.
- 3High-energy photons.
- 48 α and 6 β⁻.
- 5Nucleus takes a K electron.
- 6γ > β > α.
- 7Paper.
- 8Z − 1.
Rate of decay, decay constant and units
Like ice melting a fixed fraction per day, a radioactive sample decays by a fixed fraction.
Decay rate: A = −dN/dt = λN. Decay constant λ: unit s⁻¹. N = N₀e^(−λt). Mean life τ = 1/λ.
In the figure : Decay curve.
Rule 1: Law of decay — Decay rate is proportional to the nuclei present; N = N₀e^(−λt); ln N is linear in t.
- Easy : λ = 0.0693 d⁻¹ ⇒ t½ = 10 d.
- Medium : τ = 14.4 d.
- Exam-type : Smaller N ⇒ lower rate.
Rule 2: Units — 1 becquerel (Bq) = 1 decay/s; 1 curie (Ci) = 3.7 × 10¹⁰ Bq; 1 rutherford = 10⁶ Bq.
- Easy : 1 Ci = 3.7 × 10¹⁰ decays/s.
- Medium : 5 mCi = 1.85 × 10⁸ Bq.
- Exam-type : 1 μCi = 3.7 × 10⁴ Bq.
Rule 3: t½ and λ — t½ = 0.693/λ = 0.693τ ⇒ τ = 1.44 t½. Larger λ ⇒ shorter t½.
- Easy : t½ = 5730 y ⇒ λ = 1.21 × 10⁻⁴ y⁻¹.
- Medium : τ = 1.44 × 5730 ≈ 8250 y.
- Exam-type : Doubling λ halves t½.
Calculation: λ and τ for t½ = 10 d
- Step 1: λ = 0.693 ÷ 10 = 0.0693 d⁻¹.
- Step 2: τ = 1/λ = 14.4 d.
- Step 3: τ = 1.44 × 10 = 14.4 d ✔.
CET level (MCQ)
- CET 1) 1 Ci = ? Bq 1) 3.7×10⁷ 2) 3.7×10¹⁰ 3) 10⁶ 4) 1 — Answer: 2).
- CET 2) Unit of λ? 1) s 2) s⁻¹ 3) Bq 4) Ci — Answer: 2).
Real-life use: Medical doses, waste management.
A = λN; t½ = 0.693/λ; τ = 1.44 t½; 1 Ci = 3.7×10¹⁰ Bq.
Writing the unit of λ as s.
Rate in Bq; decay constant in s⁻¹.
Memory clue: "0.693 = ln 2".
Spot the difference
| Quantity | Unit |
|---|---|
| λ | s⁻¹ |
| Activity | Bq, Ci |
| t½, τ | s |
Practice questions
- 1State the decay law.
- 2Unit of λ?
- 31 Ci = ? Bq
- 4t½ = 10 d ⇒ λ?
- 5τ = ? (t½ = 10 d)
- 65 mCi = ? Bq
- 7Shape of ln N vs t?
- 8Meaning of larger λ?
Show answers (try them yourself first)
- 1Rate ∝ N.
- 2s⁻¹.
- 33.7 × 10¹⁰.
- 40.0693 d⁻¹.
- 514.4 d.
- 61.85 × 10⁸ Bq.
- 7Straight line, slope −λ.
- 8Shorter half-life.
Half-life, decay calculations and radiocarbon dating
The age of ancient wood is known because its ¹⁴C halves every 5730 years.
Half-life t½: the time for half the nuclei to decay. N = N₀(½)^(t/t½).
In the figure : Radiocarbon.
Half-life, decay calculations and radiocarbon dating
In the app you can move this figure with your finger.
Open in the appRule 1: Half-life calculations — N = N₀(½)ⁿ with n = t ÷ t½. Fraction left = (½)ⁿ.
- Easy : 80 g, 3 t½ ⇒ 10 g.
- Medium : t½ = 10 d, 25 d ⇒ (½)^2.5 = 17.7 %.
- Exam-type : 2 t½ ⇒ 25 %.
Rule 2: Formula method — t = (2.303/λ) log(N₀/N); λ = 0.693/t½.
- Easy : N₀/N = 4 ⇒ t = 2 t½.
- Medium : t½ = 10 d, N₀/N = 4 ⇒ 20 d.
- Exam-type : ln 2 = 0.693.
Rule 3: Radiocarbon dating — ¹⁴N + n → ¹⁴C + p in the atmosphere; living tissue keeps a constant ¹⁴C level; after death it decays. t½ = 5730 y; usable to about 50 000 y.
- Easy : 25 % left ⇒ 11 460 y.
- Medium : 50 % left ⇒ 5730 y.
- Exam-type : 12.5 % ⇒ 17 190 y.
Calculation: % left after 25 d with t½ = 10 d
- Step 1: n = 25 ÷ 10 = 2.5.
- Step 2: (½)^2.5 = 0.1768.
- Step 3: ≈ 17.7 %.
CET level (MCQ)
- CET 1) 80 g after 3 half-lives? 1) 40 2) 20 3) 10 4) 5 — Answer: 3).
- CET 2) 25 % ¹⁴C left (t½ = 5730)? 1) 5730 2) 11460 3) 17190 4) 2865 — Answer: 2).
Real-life use: Archaeology and geology.
(½)ⁿ; 25 % = 2 t½; 12.5 % = 3 t½; ¹⁴C: 5730 y.
Thinking nothing is left after two half-lives; 25 % remains.
n can be a fraction (2.5).
Memory clue: "100-50-25-12.5".
Spot the difference
| n of t½ | Fraction left |
|---|---|
| 1 | 50 % |
| 2 | 25 % |
| 3 | 12.5 % |
Practice questions
- 1What is half-life?
- 280 g after 3 t½?
- 3t½ = 10 d, 25 d ⇒ %?
- 4Age if 25 % ¹⁴C left?
- 5How is ¹⁴C formed?
- 6Limit of the method?
- 7Age for 12.5 %?
- 8Find λ for t½ = 5730 y.
Show answers (try them yourself first)
- 1Time for half to decay.
- 210 g.
- 317.7 %.
- 411 460 y.
- 5¹⁴N + n → ¹⁴C + p.
- 6≈ 50 000 y.
- 717 190 y.
- 81.21 × 10⁻⁴ y⁻¹.
Nuclear reactions, reactors and uses of radioisotopes
A nuclear power reactor and a hospital PET scan both rely on nuclear reactions.
Transmutation: one element becoming another. Fission: a heavy nucleus splitting. Fusion: light nuclei joining.
In the figure : Fission, fusion, reactor.
Rule 1: Transmutation — ¹⁴N + ⁴He → ¹⁷O + ¹H (Rutherford, 1919). A and Z balance on both sides.
- Easy : ²⁷Al + ⁴He → ³⁰P + n.
- Medium : ⁹Be + ⁴He → ¹²C + n.
- Exam-type : A: 14 + 4 = 17 + 1.
Rule 2: Fission and the reactor — ²³⁵U + n → ¹⁴¹Ba + ⁹²Kr + 3n + ≈ 200 MeV. Chain reaction; control rods (Cd, B), moderator (heavy water/graphite), coolant. 1 g of ²³⁵U ⇒ ≈ 8.2 × 10¹⁰ J.
- Easy : A: 235 + 1 = 141 + 92 + 3.
- Medium : The moderator slows neutrons.
- Exam-type : A Cd rod absorbs neutrons.
Rule 3: Fusion and radioisotopes — ²H + ³H → ⁴He + n + 17.6 MeV (> 10⁷ K). Uses: ⁶⁰Co (cancer), ¹³¹I (thyroid), ³²P (plant studies), ¹⁴C (dating).
- Easy : The Sun runs on fusion.
- Medium : ¹³¹I collects in the thyroid.
- Exam-type : ⁶⁰Co emits γ rays.
Check: balance the fission equation
- Step 1: A on the left 235 + 1 = 236; on the right 141 + 92 + 3 = 236.
- Step 2: Z on the left 92; on the right 56 + 36 = 92.
- Step 3: Both match ⇒ the equation is balanced.
CET level (MCQ)
- CET 1) A reactor moderator? 1) Cd 2) heavy water 3) U 4) Pb — Answer: 2).
- CET 2) Temperature needed for fusion? 1) 10³ K 2) 10⁵ K 3) 10⁷ K 4) 300 K — Answer: 3).
Real-life use: Power, cancer therapy, agricultural research.
Fission ≈ 200 MeV; fusion 17.6 MeV; Cd = controller; heavy water = moderator.
Confusing control rods with the moderator.
Check both A and Z in the equation.
Memory clue: "moderator slows, cadmium captures".
Spot the difference
| Item | Fission | Fusion |
|---|---|---|
| Nuclei | heavy | light |
| Energy | ≈ 200 MeV | 17.6 MeV |
| Example | reactor | Sun |
Practice questions
- 1What is transmutation?
- 2Rutherford's reaction.
- 3Write a fission equation.
- 4Role of a moderator?
- 5What are control rods made of?
- 6Condition for fusion?
- 7Use of ¹³¹I?
- 8Energy from 1 g ²³⁵U?
Show answers (try them yourself first)
- 1One element converted to another.
- 2¹⁴N + ⁴He → ¹⁷O + ¹H.
- 3²³⁵U + n → ¹⁴¹Ba + ⁹²Kr + 3n.
- 4Slow down neutrons.
- 5Cd or B.
- 6> 10⁷ K.
- 7Thyroid treatment.
- 8≈ 8.2 × 10¹⁰ J.
Quick revision of the whole lesson
| Concept | Key formula / fact |
|---|---|
| r | 1.33 A^(1/3) fm |
| Magic | 2, 8, 20, 28, 50, 82, 126 |
| BE | Δm × 931.5 MeV |
| α / β⁻ / β⁺ | A−4,Z−2 / Z+1 / Z−1 |
| Decay | A = λN |
| t½ | 0.693 / λ |
| ¹⁴C | 5730 y |
| Fission / fusion | ≈ 200 / 17.6 MeV |
🚀 Quick revision of the whole lesson
In the app you can move this figure with your finger.
Open in the app🎯 Most important points for the exam
- Nucleus and nuclides.
- Stability.
- Mass defect.
- Decay modes.
- Decay rate.
- Half-life, ¹⁴C.
- Nuclear reactions.
understand the idea → remember the formula → solve the example → solve problems yourself.